How Catalytic Converters Work
There are millions of cars on the road in the United Kingdom, and each one is potentially a source of air pollution. Especially in
large cities, the amount of pollution that all the cars produce together can create big problems.
To solve those problems, cities, states and the government create clean-air laws, and many laws have been enacted that restrict
the amount of pollution that cars can produce. To keep up with these laws, automakers have made many refinements to car
engines and fuel systems. To help reduce the emissions further, they have developed an interesting device called a catalytic
converter, which treats the exhaust before it leaves the car and removes a lot of the pollution.

Location of catalytic converter in car
In this article, you will learn which pollutants are produced by an engine and why, and how a catalytic converter deals with each of
these pollutants. Catalytic converters are amazingly simple devices, so it is incredible to see how big an impact they have!
Pollutants Produced by a Car Engine
In order to reduce emissions, modern car engines carefully control the amount of fuel they burn. They try to keep the air-to-fuel
ratio very close to the stoichiometric point, which is the calculated ideal ratio of air to fuel. Theoretically, at this ratio, all of the fuel
will be burned using all of the oxygen in the air. For Petrol, the stoichiometric ratio is about 14.7:1, meaning that for each pound of
Petrol, 14.7 pounds of air will be burned. The fuel mixture actually varies from the ideal ratio quite a bit during driving. Sometimes
the mixture can be lean (an air-to-fuel ratio higher than 14.7), and other times the mixture can be rich (an air-to-fuel ratio lower than
14.7).
The main emissions of a car engine are:
· Nitrogen gas (N2) - Air is 78-percent nitrogen gas, and most of this passes right through the car engine.
· Carbon dioxide (CO2) - This is one product of combustion. The carbon in the fuel bonds with the oxygen in the air.
· Water vapor (H2O) - This is another product of combustion. The hydrogen in the fuel bonds with the oxygen in the air.
These emissions are mostly benign (although carbon dioxide emissions are believed to contribute to global warming). But because
the combustion process is never perfect, some smaller amounts of more harmful emissions are also produced in car engines:
· Carbon monoxide (CO) - a poisonous gas that is colorless and odorless
· Hydrocarbons or volatile organic compounds (VOCs) - produced mostly from unburned fuel that evaporates
Sunlight breaks these down to form oxidants, which react with oxides of nitrogen to cause ground level ozone (O3), a major
component of smog.
· Nitrogen oxides (NO and NO2, together called NOx) - contributes to smog and acid rain, and
Three main regulated emissions, and also the ones that catalytic converters are designed to reduce.
How Catalytic Converters Reduce Pollution
Most modern cars are equipped with three-way catalytic converters. "Three-way" refers to the three regulated emissions it helps
to reduce -- carbon monoxide, VOCs and NOx molecules. The converter uses two different types of catalysts, a reduction catalyst
and an oxidization catalyst. Both types consist of a ceramic structure coated with a metal catalyst, usually platinum, rhodium and/or
palladium. The idea is to create a structure that exposes the maximum surface area of catalyst to the exhaust stream, while also
minimizing the amount of catalyst required (they are very expensive).



A three-way catalytic converter: Note the two separate catalysts.
There are two main types of structures used in catalytic converters -- honeycomb and ceramic beads. Most cars today use a
honeycomb structure.

Ceramic honeycomb catalyst structure
The Reduction Catalyst
The reduction catalyst is the first stage of the catalytic converter. It uses platinum and rhodium to help reduce the NOx emissions.
When an NO or NO2 molecule contacts the catalyst, the catalyst rips the nitrogen atom out of the molecule and holds on to it,
freeing the oxygen in the form of O2. The nitrogen atoms bond with other nitrogen atoms that are also stuck to the catalyst, forming
N2. For example:
2NO => N2 + O2 or 2NO2 => N2 + 2O2
The Oxidization Catalyst
The oxidation catalyst is the second stage of the catalytic converter. It reduces the unburned hydrocarbons and carbon monoxide
by burning (oxidizing) them over a platinum and palladium catalyst. This catalyst aids the reaction of the CO and hydrocarbons with
the remaining oxygen in the exhaust gas. For example:
2CO + O2 => 2CO2
But where did this oxygen come from?
The Control System
The third stage is a control system that monitors the exhaust stream, and uses this information to control the fuel injection system.
There is an oxygen sensor mounted upstream of the catalytic converter, meaning it is closer to the engine than the converter is.
This sensor tells the engine computer how much oxygen is in the exhaust. The engine computer can increase or decrease the
amount of oxygen in the exhaust by adjusting the air-to-fuel ratio. This control scheme allows the engine computer to make sure
that the engine is running at close to the stoichiometric point, and also to make sure that there is enough oxygen in the exhaust to
allow the oxidization catalyst to burn the unburned hydrocarbons and CO
The details contained on this page are for general information only different vehicles may have different setups to those shown. |